As an alternative to nanoscaling, here we show that two complex niobium tungsten oxides—Nb16W5O55 and Nb18W16O93, which adopt crystallographic shear and bronze-like structures, respectively—can intercalate large quantities of lithium at high rates, even when the sizes of the niobium tungsten oxide particles are of the order of micrometres.
Intercalation-type niobium tungsten oxide anodes show potential for use in high-power-density lithium-ion batteries (LIBs). Lithium activation barriers are vital factors determining the rate performance of niobium tungsten oxides.
As an alternative to nanoscaling, here we show that two complex niobium tungsten oxides—Nb16W5O55 and Nb18W16O93, which adopt crystallographic shear and bronze-like structures, respectively—can intercalate large quantities of lithium at high rates,
As an alternative to nanoscaling, here we show that two complex niobium tungsten oxides—Nb 16 W 5 O 55 and Nb 18 W 16 O 93, which adopt crystallographic shear and bronze-like structures,...
As an alternative to nanoscaling, here we show that two complex niobium tungsten oxides-Nb 16 W 5 O 55 and Nb 18 W 16 O 93, which adopt crystallographic shear and bronze-like structures, respectively-can intercalate large quantities of lithium at high rates, even when the sizes of the niobium tungsten oxide particles are of the order of micromet...
As an alternative to nanoscaling, here we show that two complex niobium tungsten oxides-Nb16W5O55 and Nb18W16O93, which adopt crystallographic shear and bronze-like structures,...
Micrometre-sized particles of two niobium tungsten oxides have high volumetric capacities and rate performances, enabled by very high lithium-ion diffusion coefficients. The maximum power output and minimum charging time of a lithium-ion battery depend on both ionic and electronic transport.
Multielectron redox, buffered volume expansion, and extremely fast lithium transport approaching that of a liquid lead to extremely high volumetric capacities and rate performance for both crystallographic shear structure and bronze-like niobium tungsten oxides. The active materials Nb16W5O55 and Nb18W16O93 offer new strategies toward designing
In this work, niobium tungsten oxides (WNb 2 O 8, W 3 Nb 14 O 44, and W 10.3 Nb 6.7 O 47) featured with different structural openings are selected as model systems to investigate the role of crystal structures in their lithium ion storage behaviors.
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